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Wear
Wear
Initial
contact between mating metal parts results in momentary welding
of asperities (peaks) on each surface. As each part continues
to move, the welded asperities are ripped off, leaving behind
minute pits.
Every
bearing and wear surface, no matter how smooth the finish, has
asperities. The problem is common to impellers and housings,
air cylinder pistons, machine slides, telescopic mechanisms,
ball joints, plungers, gear teeth, hinges, journal bearings,
valves, power screws.
Xylan
coatings provide a thin layer of lubrication to prevent the
asperities on mating surfaces from making physical contact with
each other. The selection of the best dry lubricant —
PTFE, moly, or graphite — for these applications depends
primarily on the PV (Pressure x Velocity), atmosphere and temperature
of the application.
In
many cases, a dry film provides enough lubrication to eliminate
objectionable wear. For example, a molded nylon detent for an
automotive signal harness was failing prematurely due to heavy
loads on the point of the detent. The sliding coefficient of
friction between the detent and its mating cam was approximately
0.40, which resulted in severe abrasive wear.
When
a 10 micron/0.0004 in. coating of a PTFE-bearing Xylan was applied
to the detent, the coefficient of friction dropped to 0.12,
and detent life was increased by over 200 percent.
Wear
is often severe in bearing-type applications. Rods that slide
through glands, rolling element bearings, slide assemblies,
telescopic booms, ball reversers, rocker arms, ball joints,
tracks, bushings and literally thousands of other applications
are configured so that one part rolls or slides over another
part.
In
most cases, friction and wear of the parts are reduced when
one or both are coated with a dry-film lubricant. Also, the
coatings serve as a thin cushion, spreading high point loads
in bearings and reducing element fatigue.
The
energy that is transmitted and dissipated in a bearing is a
function of the PV of the application. As the PV increases,
so do heat and wear on the bearing surfaces.
Dry
lubricants have a "limiting PV value" that they can
withstand for a reasonable wear life. Typically, the highest
limiting PV which a 25 micron/ 0.001 in. coating of Xylan can
withstand is approximately 50,000 (PV). This limiting value
varies from coating to coating.
There
are two additional factors to consider. First: The ability of
a coating to bear loads increases as thickness decreases. For
instance, although a 25 micron/0.001 in. film may be able to
bear PV of only 50,000, a 5 micron/0.0002 in. film (the practical
lower limit using current application techniques) may be able
to bear PV of 150,000. For this reason, the PV tolerance of
a coating may be modified by the film thickness.
Second:
The lubricants themselves. PV limits are not constant. They
tend to increase with pressure and decrease with speed.
This
is particularly true with moly coatings, which work better under
high pressure and low speed, where galling is the principal
reason for failure. Thus, with these coatings, a "speed
factor" is necessary for final computation of the PV limit
of the coating.
The
wear rates of many of the Xylan 1000, 1400 and 1600 Series coatings
are equal to that of bronze/steel bearings impregnated with
PTFE-lead when applied in thin films (17.5 microns/0.0007 in.).
When
specifying a coating for a bearing application, apply the coating
to the larger "swept" area. This spreads the wear
over a larger area and provides the greater amount of lubrication.
For
break-in, frequent starts and marginal lubrication, remember:
the period of greatest wear to a moving mechanism is when it
is new. Even fluoropolymer coatings can benefit from secondary
lubrication under these conditions.
Boundary
lubrication failure
When equipment is started and stopped frequently, oil films
tend to become too thin to function as effective lubricants
and bring sliding metal surfaces almost into contact (a condition
known as "boundary lubrication"). If metal-to-metal
contact occurs, the condition becomes "boundary lubrication
failure".
A
thin coating of Xylan reduces the chance of failure and lengthens
the life of such products as sprockets, seal plates for compressors,
pump pistons, cams, ball joints, conveyor trolleys, gears, journal
bearings — even though the anticipated PV limit of the
application is far greater than the coating can endure.
These
coatings solved wear problems under start/stop conditions in
reciprocating plungers in electrical solenoids. Typical plungers
are chrome plated (and extremely hard). But the starting and
stopping at the end of each half-cycle put the plunger into
boundary lubrication failure, causing the plating to wear rapidly.
When a matrix coating replaced chrome plating, boundary lubrication
failure was overcome and plunger life was extended by 90 percent.
A
maker of chain saws uses Xylan 1010 as a fail-safe lubricant
on the cage of the saw's main bearing. Clearance between the
cage and connecting rod is only 100 to 150 microns/0.004 to
0.006 in. When the engine started, the bearing was in boundary
lubrication. Without the coating, it tended to seize. As proof
of the coating's ruggedness, these engines run eight hours per
day and have a life expectancy of three years.
A
PTFE-type Xylan coating is recommended for applications where
initial wear is anticipated to be light to moderate; a moly-type
coating is recommended for conditions of heavy wear, especially
in high-load situations.
Fail-safe
In any circumstance in which a mechanism must function when
needed, even if only once, Xylan coatings provide a good margin
of security, even under the most critical circumstances. This
includes such aircraft parts as bearings for turbine engines,
solenoids, seat ejectors, actuators, door pins and firing mechanisms
for ordnance.
Another
category is equipment which would be damaged were a component
to fail. For example, removing a frozen bolt from chemical processing
equipment could cause damage costing thousands of times more
than the bolt. In refinery equipment, the use of a wrench is
infinitely safer than the use of a cutting torch.
A
good rule of thumb: Apply coatings of approximately 25 microns/0.001
in. to the surfaces of these parts. This ensures that the component
will function when required, and also provides good release
and excellent corrosion protection.
Note:
Definitions of any technical terms used on this page can be found
in our
glossary.

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